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Try going to “Settings > Permalinks” and clicking “Save” without changing anything. I can’t verify that it’s not working because it appears that you must be logged in to view your site.

Though, if you want to use the default archive of the staff members like that, you’ll likely want to create an archive template file in your theme directory – it would need to be named ‘archive-staff-member.php’ But you’ll be responsible for writing the code (HTML and PHP) that pulls the custom data from the Staff Member fields.

The alternative is to use the [simple-staff-list] on an existing page and then use the “Staff Loop Template” to control the structure of you staff list.

Let me know if you have more questions.