There’s no built-in setting to enable forms only on Desktop and disable them on mobile/smartphones. It would be great if you could add it as a suggestion/enhancement request on our feedback/ideas board here: https://feedback.mailpoet.com
For now, the best option might be to try to target the form on mobile only and not display it via CSS.
If you need help with custom code, we recommend reaching out to someone from Codeable: https://codeable.io