Create a stylesheet in your theme directory called ‘tinymce.css’ (for example). Add your desired link classes in there, like so:
a.myClass {}
Then, in your functions.php add the following:
function addTinyMCELinkClasses( $wp ) {
$wp .= ',' . get_bloginfo('stylesheet_directory') . '/tinymce.css';
return $wp;
}
if ( function_exists( 'add_filter' ) ) {
add_filter( 'mce_css', 'addTinyMCELinkClasses' );
}
Hope that helps.